HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Tert-Butylaniline → 4-t-Butylbenzenediazonium tetrafluoroborate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Tert-Butylaniline | HCID 69861 | — |
| Reactant | Potassium Bromide | HCID 253877 | — |
| Reactant | Nitrilooxonium tetrafluoroborate | HCID 11137142 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 4-t-Butylbenzenediazonium tetrafluoroborate | HCID 11184221 | 78% |
Reaction Steps
The 4-tert-butylaniline was dissolved in a 1:1 mixture of acetonitrile and dry methylene chloride prior to addition to the nitrosonium tetrafluoroborate. Yield: 78%. MP 91° C. IR (KBr) 3364.8, 3107.3, 2968.6, 2277.2, 1579.2, 1482.0, 1418.0, 1373.5, 1269.8, 1056.9, 841.1, 544.6, 621.4 cm−1. 1H NMR (400 MHz, CD3CN) δ 8.16 (ABq, J=9.0 Hz, Δν=298.7 Hz, 4H), 1.30 (s, 12H). 13C NMR (100 MHz, CD3CN) δ 168.85, 133.67, 130.43, 111.88, 37.86, 30.84.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07892517B2 |
| Source dataset | uspto-grants-2011_02 |
| ORD ID | ord-a20d247756a74f6c92f07d9c962fc88f |
| Source note | uspto-grants-2011_02 |