Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
p-Tetradecylaniline → 4-Tetradecylbenzenediazonium tetrafluoroborate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | p-Tetradecylaniline | HCID 145224 | — |
| 반응물 | Potassium Bromide | HCID 253877 | — |
| 반응물 | Nitrilooxonium tetrafluoroborate | HCID 11137142 | — |
| 용매 | Acetonitrile | HCID 6342 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 4-Tetradecylbenzenediazonium tetrafluoroborate | HCID 44887953 | 69% |
반응 단계
The 4-tetradecylaniline was dissolved in a 1:1 mixture of acetonitrile and dry methylene chloride prior to addition to the nitrosonium tetrafluoroborate. Yield: 69%. MP 82° C. IR (KBr) 3103.8, 2919.5, 2289.6, 1577.8, 1473.7, 1070.8, 1024.8, 844.5, 813.8, 716.9, 541.0, 510.2 cm−1. IR (KBr) 3103.8, 2919.5, 2289.6, 1577.8, 1473.7, 1070.8, 1024.8, 844.5, 813.8, 716.9, 541.0, 510.2 cm−1. 1H NMR (400 MHz, CDCl3) δ 8.02 (ABq, J=8.8 Hz, Δν=370.6 Hz, 4H), 2.76 (t, J=7.7 Hz, 2H), 1.61 (quin, J=7.8 Hz, 2H), 1.23 (s, 22H), 0.85 (t, J=7.0 Hz, 3H). 13C NMR (100 MHz, CDCl3) δ 159.92, 133.26, 131.94, 110.96, 37.49, 32.34, 30.87, 30.12, 30.10, 30.07, 30.04, 29.91, 29.78, 29.75, 29.72, 23.11, 14.55.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07892517B2 |
| 출처 데이터셋 | uspto-grants-2011_02 |
| ORD ID | ord-f68d16ca8340421692d499dc74c40f5f |
| 출처 메모 | uspto-grants-2011_02 |