HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1369357Generated: October 25, 2026
Triethylamine → 2-Methyladamantan-2-yl Acrylate (stabilized with MEHQ)
https://huagongshe.com/reaction/1369357
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Acryloyl chloride | HCID 13140 | — |
| Reactant | 2-Methyl-2-adamantanol | HCID 136545 | — |
| Solvent | Methyl Isobutyl Ketone | HCID 7909 | — |
| Product | 2-Methyladamantan-2-yl Acrylate (stabilized with MEHQ) | HCID 11218292 | 92% |
Reaction Steps
166 g of 2-Methyl-2-adamantanol, 303 g of triethylamine and 500 g of methylisobutyl ketone were mixed by stirring at 60° C. While stirring, 136 g of acrylic acid chloride was added dropwise to the mixture. After completion of the dropwise addition, the mixture was stirred for six more hours. Then, extraction and distillation were conducted to obtain 2-methyl-2-adamantyl acrylate at the yield of 92%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US06579659B2 |
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| Source dataset | uspto-grants-2003_06 |
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| ORD ID | ord-f774d4603a0442d0bdca4e7132dd665b |
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| Source note | uspto-grants-2003_06 |
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