MLS003373810 → N,N,N',N'-Tetramethyltetramethylenediamine

HRID 1370687Notes

Reaction equation

C[Si](OC(C1S[C@H]2N(C(=O)[C@H]2N[Si](C)(C)C)C=C1/C=C/CI)=O)(C)C.[CH2:26]([N:36]1[CH2:41]COC[CH2:37]1)[CH2:27][CH2:28][CH2:29][N:30]1[CH2:35]COC[CH2:31]1>>[CH3:31][N:30]([CH3:35])[CH2:29][CH2:28][CH2:27][CH2:26][N:36]([CH3:41])[CH3:37]

Participants

Reactant 2

HCID 349308MLS003373810

HCID 70029530HCID 70029530, compound

Product 1

HCID 66074N,N,N',N'-Tetramethyltetramethylenediamine

Procedure

By operating in an analogous manner to the procedure described in Examples 56-81(a), (E)-(6R,7R)-3-(3-iodo-propenyl)-8-oxo-7-trimethylsilanylamino-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-4-carboxylic acid trimethylsilanyl ester was reacted with 4,4′-butane-1,4-diyl-bis-morpholine, and with N,N,N′,N′-tetramethyl-1,4-butanediamine, respectively, to give

Sources & evidence

ORD record: ord-4e3b0158e1544b1980438af4202aef54
Source dataset: uspto-grants-2003_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06583133B1

Reaction notes

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