HCID 11277604, compound → HCID 11736637, compound

HRID 1370772Notes

Reaction equation

HRID 1370772 reaction equation
CON(C)[C:4]([C@@H:6]1[CH2:8][C@H:7]1[C:9]1[C:18]2[C:13](=[CH:14][CH:15]=[C:16]([O:19][CH3:20])[CH:17]=2)[CH:12]=[CH:11][CH:10]=1)=[O:5].CC([O-:26])(C)C.[K+]>CCOCC>[CH3:20][O:19][C:16]1[CH:17]=[C:18]2[C:13]([CH:12]=[CH:11][CH:10]=[C:9]2[C@@H:7]2[CH2:8][C@H:6]2[C:4]([OH:5])=[O:26])=[CH:14][CH:15]=1

Participants

4

Reactant 2

HCID 11277604HCID 11277604, compoundHCID 23665647Potassium tert-butoxide

Product 1

HCID 11736637HCID 11736637, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

6 g (21 mmol) of the compound obtained in Step G in 50 ml of anhydrous ether and 15.4 g of potassium tert-butylate are stirred for 2 days at room temperature. 3.2 g of a light brown solid are collected and reacted without purification.

Workup

  1. custom3.2 g of a light brown solid are collected
  2. customreacted without purification

Sources & evidence

ORD record
ord-eeace4fcc43e4777b4feeb1386df0411
Source dataset
uspto-grants-2003_06
Patent number
US06583319B1

Reaction notes

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