2-Methyl-3-nitroaniline → N-(4-(3-(allyloxy)phenoxy)benzyl)-2-methyl-3-nitroaniline

HRID 1370832Notes

Reaction equation

HRID 1370832 reaction equation
[CH2:1]([O:4][C:5]1[CH:6]=[C:7]([CH:17]=[CH:18][CH:19]=1)[O:8][C:9]1[CH:16]=[CH:15][C:12]([CH:13]=O)=[CH:11][CH:10]=1)[CH:2]=[CH2:3].[CH3:20][C:21]1[C:27]([N+:28]([O-:30])=[O:29])=[CH:26][CH:25]=[CH:24][C:22]=1[NH2:23]>>[CH2:1]([O:4][C:5]1[CH:6]=[C:7]([CH:17]=[CH:18][CH:19]=1)[O:8][C:9]1[CH:16]=[CH:15][C:12]([CH2:13][NH:23][C:22]2[CH:24]=[CH:25][CH:26]=[C:27]([N+:28]([O-:30])=[O:29])[C:21]=2[CH3:20])=[CH:11][CH:10]=1)[CH:2]=[CH2:3]

Participants

3

Reactant 2

HCID 117832-Methyl-3-nitroanilineHCID 185123024-[3-(Allyloxy)phenoxy]benzaldehyde

Product 1

HCID 18512125N-(4-(3-(allyloxy)phenoxy)benzyl)-2-methyl-3-nitroanilineYield 82%

Procedure

The product from Example 61C and 2-methyl-3-nitroaniline were processed as described in Example 6A to provide the title compound (7.20 g, 82%).

Sources & evidence

ORD record
ord-bf5533edd7e84a29aba169442e48f929
Source dataset
uspto-grants-2003_06
Patent number
US06583180B2

Reaction notes

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