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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1371571Generated: October 25, 2026

Methyl 3,4-bis(bromomethyl)benzoate → Methyl 13-oxotricyclo[8.2.1.0(3),8]trideca-3(8),4,6-triene-5-carboxylate

https://huagongshe.com/reaction/1371571

Reaction equation

Participants

RoleNameHCIDCharge
ReactantMethyl 3,4-bis(bromomethyl)benzoateHCID 2736819—
ReactantTricyclo[8.2.1.03,8]trideca-3,5,7-trien-13-oneHCID 5260406—
ProductMethyl 13-oxotricyclo[8.2.1.0(3),8]trideca-3(8),4,6-triene-5-carboxylateHCID 21882835—

Reaction Steps

Prepared using the procedure described for 11-oxo-5,6,7,8,9,10-hexahydro -6,9-methanobenzocyclooctene (Justus Liebigs Ann. Chem. 1961, 650, 115) using methyl 3,4-bis(bromomethyl)benzoate in place of 1,2-bis(bromomethyl)benzene.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS07157478B2
Source datasetuspto-grants-2007_01
ORD IDord-6171ed4c99a941af9be82d4fee9d6d6a
Source noteuspto-grants-2007_01