関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 2,4,6-Trimethylaniline | HCID 6913 | — |
| 反応物 | Sodium Acetate | HCID 517045 | — |
| 反応物 | HCID 14150053 | HCID 14150053 | — |
| 触媒 | Cuprous acetate | HCID 69023 | — |
| 生成物 | HCID 21072034 | HCID 21072034 | — |
反応手順
37 g of 1,3,5,7-tetrabromoanthraquinone, 12.3 ml of mesidine, 17.3 g of sodium acetate and 0.5 g of copper(I) acetate are introduced into a laboratory reaction apparatus and stirred for 7 hours at 170° C. After cooling to RT, the crude product is precipitated by the addition of 1 liter of 2N HCl and recrystallised from ethanol. After filtration and drying 21 g (47%) of product are obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07160335B2 |
|---|
| 出典データセット | uspto-grants-2007_01 |
|---|
| ORD ID | ord-b94493d987b541dfaa2ef7aedb8de1e2 |
|---|
| 出典メモ | uspto-grants-2007_01 |
|---|
