Sodium Fluoride → 2,3,3,3-Tetrafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propanoyl fluoride

HRID 1373464Notes

Reaction equation

HRID 1373464 reaction equation
C(C(C(OC(C([O:20][C:21]([C:24]([O:30][C:31]([C:34]([C:37]([F:40])([F:39])[F:38])([F:36])[F:35])([F:33])[F:32])([C:26]([F:29])([F:28])[F:27])[F:25])(F)[F:22])=O)(C(F)(F)F)F)(F)F)(F)F)(F)(F)F.[F-].[Na+]>>[C:37]([C:34]([C:31]([O:30][C:24]([C:21]([F:22])=[O:20])([C:26]([F:29])([F:28])[F:27])[F:25])([F:33])[F:32])([F:36])[F:35])([F:40])([F:39])[F:38]

Participants

3

Reactant 2

HCID 5235Sodium FluorideHCID 11422460HCID 11422460, compound

Product 1

HCID 1027402,3,3,3-Tetrafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propanoyl fluoride

Conditions

Temperature
140 °C

Procedure

The reaction product containing CF3CF2CF2OCF(CF3)—COOCF2CF(CF3)OCF2CF2CF3 (83.0 g) obtained in Example 1-2 was charged together with NaF powder (1.1 g) into a flask and heated at 140° C. for 15 hours in an oil bath, while vigorously stirring. At an upper portion of the flask, a liquid sample (81.3 g) was recovered through a reflux condenser having the temperature adjusted to 70° C. A product obtained by distilling the liquid sample for purification was analyzed by GC-MS, whereupon formation of CF3CF2CF2OCF(CF3)COF was confirmed.

Workup

  1. customAt an upper portion of the flask, a liquid sample (81.3 g) was recovered through a reflux condenser
  2. customadjusted to 70° C
  3. customA product obtained
  4. distillationby distilling the liquid sample
  5. customfor purification

Sources & evidence

ORD record
ord-f9ebedbe2bfb4da3becc974b4ae2a6b0
Source dataset
uspto-grants-2007_01
Patent number
US07161025B2

Reaction notes

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