HCID 178443572, compound → HCID 178420579, compound

HRID 1373674Notes

Reaction equation

HRID 1373674 reaction equation
[Cl-:1].[Cl-].C([Hf:11]([SiH2]C1C=CC=CC=1)([CH:21]1[C:29]2[C:24](=CC=CC=2)[CH:23]=[CH:22]1)[CH:12]1[C:20]2[C:15](=CC=CC=2)[CH:14]=[CH:13]1)CCCCCCC>[Cl-].[Cl-].C(C1([Zr+2]C2(CCCC)C=CC=C2)C=CC=C1)CCC.[Cl-].[Cl-].C[SiH]([Zr+2](C1C2C(=CC=CC=2)C=C1)C1C2C(=CC=CC=2)C=C1)C.[Cl-].[Cl-].C[SiH]([Zr+2](C1C2C(=CC=CC=2)C=C1C)C1C2C(=CC=CC=2)C=C1C)C.C1([Ti](Cl)(OCC)OCC)C2C(=CC=CC=2)C=C1.[Cl-].[Cl-].CC1C([Zr+2]C2(C)C(C)=C(C)C(C)=C2C)(C)C(C)=C(C)C=1C.[Cl-].[Cl-].C1([Zr+2]C2C3C(=CC=CC=3)C=C2)C2C(=CC=CC=2)C=C1.[Cl-].[Cl-].C[Zr]([SiH2]CCCCCCCC)(C1C2C=CC=CC=2C2C1=CC=CC=2)C1C2C=CC=CC=2C2C1=CC=CC=2>[Cl-:1].[Cl-:1].[CH:21]1([Hf+2:11][CH:12]2[CH:20]=[CH:15][CH:14]=[CH:13]2)[CH:22]=[CH:23][CH:24]=[CH:29]1

Participants

9

Reactant 1

HCID 178443572HCID 178443572, compound

Product 1

HCID 178420579HCID 178420579, compound

Reagents, catalysts & solvents 7

HCID 178420590HCID 178420590, compoundCatalyst2×HCID 178421914HCID 178421914, compoundCatalystHCID 178426003HCID 178426003, compoundCatalystHCID 178442027HCID 178442027, compoundCatalystHCID 178443888HCID 178443888, compoundCatalystHCID 178477242HCID 178477242, compoundCatalystHCID 178504580HCID 178504580, compoundCatalyst

Procedure

1,2-ethanediylbis(η5-1-indenyl)di-n-butoxyhafnium; 1,2-ethanediylbis(η5-1-indenyl)dimethylzirconium; 3,3-pentanediylbis((η5-4,5,6,7-tetrahydro-1-indenyl)hafnium dichloride; methylphenylsilylbis(η5-4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride; bis(n-butylcyclopentadienyl)bis(di-t-butylamido)hafnium; bis(n-butylcyclopentadienyl)zirconium dichloride; dimethylsilylbis(1-indenyl)zirconium dichloride; octylphenylsilylbis(1-indenyl)hafnium dichloride; dimethylsilylbis(η5-4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride; dimethylsilylbis(2-methyl-1-indenyl)zirconium dichloride; 1,2-ethanediylbis(9-fluorenyl)zirconium dichloride; indenyl diethoxy titanium(IV) chloride; (isopropylamidodimethylsilyl)cyclopentadienyltitanium dichloride; bis(pentamethylcyclopentadienyl)zirconium dichloride; bis(indenyl)zirconium dichloride; bis(indenyl)zirconium dichloride; methyloctylsilyl bis(9-fluorenyl)zirconium dichloride; bis-[1-(N,N-diisopropylamino)boratebenzene]hydridozirconium trifluoromethylsulfonate; or any combination thereof.

Sources & evidence

ORD record
ord-c07ada853d2e4aa5b59096381eac9fa2
Source dataset
uspto-grants-2007_01
Patent number
US07163906B2

Reaction notes

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