HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Carbonate → 1,4,5-Triphenyl-2-(6-bromohexyloxy)imidazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 1,4,5-Triphenyl-1,3-dihydro-2H-imidazol-2-one | HCID 628544 | — |
| Reactant | 1,1-Dibromohexane | HCID 11806854 | — |
| Solvent | Methyl Ethyl Ketone | HCID 6569 | — |
| Product | 1,4,5-Triphenyl-2-(6-bromohexyloxy)imidazole | HCID 22916370 | 29.4% |
Reaction Steps
A mixture of 1,4,5-triphenylimidazol-2-one (6.25 g), dibromohexane (24.4 g) and potassium carbonate (5.53 g) in dry butanone (300 ml) was heated at reflux temperature for 24 hours. The mixture was cooled and the flitrate evaporated to an oil which was chromatographed on silica gel (hexaneyethyl acetate) to give 1,4,5-triphenyl-2-(6-bromohexyloxy)-imidazole (2.8 g, 29%) as a white solid, m.p. 87°-9° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05663053 |
| Source dataset | uspto-grants-1997_09 |
| ORD ID | ord-c1815394dbf94b439126ecf3461fd303 |
| Source note | uspto-grants-1997_09 |