HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Carbonate → 7-(3,4,5-Triphenyl-2-oxo-2,3-dihydroimidazol-1-yl)heptanonitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | Heptanenitrile, 7-bromo- | HCID 88737 | — |
| Reactant | 1,4,5-Triphenyl-1,3-dihydro-2H-imidazol-2-one | HCID 628544 | — |
| Product | 7-(3,4,5-Triphenyl-2-oxo-2,3-dihydroimidazol-1-yl)heptanonitrile | HCID 22916372 | — |
Reaction Steps
1,4,5-TriphenylimidazoI-2-one was treated with 7-bromo-heptanonitrile and potassium carbonate in bumone to give after chromatographic work-up 7-(3,4,5-triphenyl-2-oxo-2,3-dihydroimidazol-1-yl)heptanonitrile, m.p. 100°-101° C., Found: C, 79.7; H, 6.6; N, 9.8%; C28H27N3O requires: C, 79.9; H, 6.4; N, 10.0%; and 7-(1,4,5-triphenylimidazol-2-yloxy)heptanonitrile, m.p..93°-94° C., Found: C, 79.5; H, 6.6; N, 9.7%; C28H27N3O requires: C, 79.9; H, 6.4; N, 10.0%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05663053 |
| Source dataset | uspto-grants-1997_09 |
| ORD ID | ord-ccca8a66dcff42fba60fc0ee1a99f1f9 |
| Source note | uspto-grants-1997_09 |