Solketal → (2,2-Dimethyl-1,3-dioxolan-4-yl)methyl methanesulfonate

HRID 1376439Notes

Reaction equation

[CH3:1][C:2]1([CH3:9])[O:6][CH:5]([CH2:7][OH:8])[CH2:4][O:3]1.[CH3:10][S:11](Cl)(=[O:13])=[O:12]>>[CH3:10][S:11]([O:8][CH2:7][CH:5]1[CH2:4][O:3][C:2]([CH3:9])([CH3:1])[O:6]1)(=[O:13])=[O:12]

Participants

Reactant 2

HCID 7528Solketal

HCID 31297Methanesulfonyl chloride

Product 1

HCID 15570840(2,2-Dimethyl-1,3-dioxolan-4-yl)methyl methanesulfonate

Procedure

reacting an optically active isomer of 2,2-dimethyl-1,3-dioxolane-4-methanol with methanesulphonyl chloride to obtain the corresponding (2,2-dimethyl-1,3-dioxolan-4-yl)methyl methanesulphonate;

Sources & evidence

ORD record: ord-9623c9c9e11440f188f116cd028b04b8
Source dataset: uspto-grants-1997_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05663173

Reaction notes

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