1,3-dioxan-5-one → 2,2-Dimethyl-1,3-dioxan-5-one

HRID 1376900Notes

Reaction equation

HRID 1376900 reaction equation
O1CC(=O)COC1.[CH2:8]([C:10]1([CH2:17]C)[O:15][CH2:14][C:13](=[O:16])[CH2:12][O:11]1)C.O1C2(CCCCC2)OCC(=O)C1>>[CH3:8][C:10]1([CH3:17])[O:15][CH2:14][C:13](=[O:16])[CH2:12][O:11]1

Participants

4

Reactant 3

HCID 97937071,3-dioxan-5-oneHCID 113212061,5-dioxaspiro[5.5]undecan-3-oneHCID 19078650HCID 19078650, compound

Product 1

HCID 27331412,2-Dimethyl-1,3-dioxan-5-one

Procedure

By working in a similar way but using 1,3-dioxan-5-one, 2,2-diethyl-1,3-dioxan-5-one and 1,5-dioxaspiro[5,5]undecan-3-one, in place of 2,2-dimethyl-1,3-dioxan-5-one, the following compounds were respectively obtained: 1,3-dioxan-5-one oxime, 2,2-diethyl-1,3-dioxan-5-one oxime and 1,5-dioxaspiro[5,5]undecan-3-one oxime.

Sources & evidence

ORD record
ord-91af62f6bed24581a912f9985eb7dbbb
Source dataset
uspto-grants-1997_09
Patent number
US05663372

Reaction notes

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