Pyridine → HCID 23191324, compound

HRID 1378894Notes

Reaction equation

HRID 1378894 reaction equation
[CH3:1][O:2][CH:3]([O:5][C:6]1[CH:13]=[CH:12][C:9]([CH:10]=[CH2:11])=[CH:8][CH:7]=1)[CH3:4].[CH3:14]OC(C)=C.N1C=CC=CC=1.ClS(O)(=O)=O>O1CCOCC1>[CH3:1][O:2][C:3]([CH3:14])([O:5][C:6]1[CH:7]=[CH:8][C:9]([CH:10]=[CH2:11])=[CH:12][CH:13]=1)[CH3:4].[OH:5][C:6]1[CH:13]=[CH:12][C:9]([CH:10]=[CH2:11])=[CH:8][CH:7]=1

Participants

6

Reactant 4

HCID 1049PyridineHCID 83002-MethoxypropeneHCID 24638Chlorosulfonic acidHCID 22057201HCID 22057201, compound

Product 1

HCID 23191324HCID 23191324, compound

Reagents, catalysts & solvents 1

HCID 312751,4-DioxaneSolvent

Procedure

To a solution of poly(p-hydroxystyrene) (4.0 g) obtained in the same manner as described in Synthesis Example 3, (2) and 2-methoxy-1-propene (4.8 g) in a mixed solvent (35 ml) of pyridine and 1,4-dioxane, a catalytic amount of chlorosulfonic acid was added and then reacted with stirring at room temperature for 20 hours. After reaction, the reaction was carried out in the same manner as described in Synthesis Example 2, (3) to give 4.1 g of poly[p-(1-methoxy-1-methylethoxy)styrene/p-hydroxystyrene as a white powder having Mw 10000 (GPC with polystyrene calibration). The composition of the polymer was found to be p-(1-methoxy-1-methylethoxy)styrene unit and p-hydroxystyrene unit in a molar ratio of ca. 1:1 based on 1 HNMR.

Workup

  1. customreacted
  2. customAfter reaction

Sources & evidence

ORD record
ord-c12aa2ccea454d5290683fabdc16ef37
Source dataset
uspto-grants-1997_09
Patent number
US05670299

Reaction notes

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