Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Cyclohexyl bromoacetate | HCID 221279 | — |
| Reactant | Benzenesulfinic acid, sodium salt, dihydrate | HCID 23681562 | — |
| Solvent | Dimethyl Sulfoxide | HCID 679 | — |
| Product | Cyclohexyl benzenesulfonylacetate | HCID 22908638 | 76.9% |
Reaction Steps
To a solution of cyclohexyl bromoacetate (15.6 g, 0.0705 mole) in dimethylsulfoxide (120 ml), sodium benzenesulfinate dihydrate (15 g, 0.075 mole) was added in a small portion at 20°-40° C., and reacted with stirring at 60° C. for 6 hours. After cooling, the reaction mixture was poured into cold H2O (1.5 liter). The precipitate was filtered, washed with H2O and dried to give 15.3 g of cyclohexyl benzenesulfonylacetate as a white crystals having a melting point of 35°-38° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US05670299 |
|---|
| Source dataset | uspto-grants-1997_09 |
|---|
| ORD ID | ord-71061f727e844b0a808540d031d731ba |
|---|
| Source note | uspto-grants-1997_09 |
|---|
