HCID 13187346, compound → HCID 13187370, compound

HRID 1379976Notes

Reaction equation

HRID 1379976 reaction equation
[Cl:1][CH2:2][C:3]([C:5]1[CH:10]=[CH:9][C:8]([N+:11]([O-:13])=[O:12])=[CH:7][CH:6]=1)=[CH2:4]>C1(C)C=CC=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.[Cl-].[Rh]>[Cl:1][CH2:2][CH:3]([C:5]1[CH:10]=[CH:9][C:8]([N+:11]([O-:13])=[O:12])=[CH:7][CH:6]=1)[CH3:4]

Participants

4

Reactant 1

HCID 13187346HCID 13187346, compound

Product 1

HCID 13187370HCID 13187370, compound

Reagents, catalysts & solvents 2

HCID 84599Chlorotris(triphenylphosphine)rhodium(I)CatalystHCID 1140TolueneSolvent

Procedure

A solution of 51.3 g (0.26 Mol) of 4(1-chloromethyl-ethenyl)-nitrobenzene and 10 g of tris(triphenylphosphine)-rhodium (I) chloride in 1000 ml of dry toluene is hydrogenated at ambient temperature and atmospheric pressure.

Workup

  1. customis hydrogenated at ambient temperature

Sources & evidence

ORD record
ord-f7ec7062683c449c8b70df5cf53bfac9
Source dataset
uspto-grants-1986_04
Patent number
US04579585

Reaction notes

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