Thiocarbonic acid, anhydrosulphide with methyl thiohypochlorite → HCID 13604347, compound

Participants

Reaction Steps

To a solution of 6.7 g of 1-(3-mercaptopropyl-5-phenyl-2-imidazolidinone in 70 ml of methanol, cooled to 0°, there is added dropwise 3.9 g of methoxy carbonylsulfenyl chloride over a fifteen minute period. The solution is allowed to stir at 0° for 1 hour and at room temperature for four hours. The reaction is concentrated in vacuo and the residual oil eluted on a silica gel column with ethyl acetate. The product is purified further by recrystallization from isopropyl ether, m.p. 98°-100° C.

Provenance & Evidence