HRID1380706

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID8471

Triethylamine

C6H15N

HCID74207

Benzene, (dichlorosilyl)-

C6H6Cl2Si

结构：CC(C)(C)c1cc(Cc2cc(C(C)(C)C)cc(C(C)(C)C)c2O)c(O)c(C(C)(C)C)c1

HCID84391

2,2′-Methylenebis[4,6-bis(1,1-dimethylethyl)phenol]

C29H44O2

PRODUCTS

生成物

结构：CC(C)(C)c1cc2c(c(C(C)(C)C)c1)O[SiH](c1ccccc1)Oc1c(cc(C(C)(C)C)cc1C(C)(C)C)C2

HCID131714147

未命名化合物

收率 64.3%

PROCEDURE

实验过程

Utilizing the procedure of Example 1, this compound is prepared from 17.7 grams (0.1 mole) of dichlorophenylsilane, 42.5 grams (0.1 mole) of 2,2'-methylenebis(4,6-di-t-butylphenol) and 20.2 grams (0.20 mole) of triethylamine. Recrystallization twice from acetonitrile-toluene yields 34.0 grams (64% yield) of product as an off white powder, mp 153°-156° C.; IR: 2200 cm-1SiH.

WORKUP

后处理

customRecrystallization twice from acetonitrile-toluene

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-5db59391d9ff4c1d9370aab3ee4b2a84
来源数据集: uspto-grants-1986_04
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04582870
来源说明: uspto-grants-1986_04

反应 SMILES

Cl[SiH:2](Cl)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH2:10]([C:26]1[CH:31]=[C:30]([C:32]([CH3:35])([CH3:34])[CH3:33])[CH:29]=[C:28]([C:36]([CH3:39])([CH3:38])[CH3:37])[C:27]=1[OH:40])[C:11]1[CH:16]=[C:15]([C:17]([CH3:20])([CH3:19])[CH3:18])[CH:14]=[C:13]([C:21]([CH3:24])([CH3:23])[CH3:22])[C:12]=1[OH:25].C(N(CC)CC)C>>[C:32]([C:30]1[CH:29]=[C:28]([C:36]([CH3:39])([CH3:38])[CH3:37])[C:27]2[O:40][SiH:2]([C:3]3[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=3)[O:25][C:12]3[C:13]([C:21]([CH3:23])([CH3:22])[CH3:24])=[CH:14][C:15]([C:17]([CH3:20])([CH3:19])[CH3:18])=[CH:16][C:11]=3[CH2:10][C:26]=2[CH:31]=1)([CH3:35])([CH3:34])[CH3:33]