HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → 2,4,8,10-Tetra-t-butyl-6-phenyl-dibenzo[d,g][1,3,2,6]dioxasilathiocin
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Dichloro(phenyl)silane | HCID 74207 | — |
| Reactant | 4,4',6,6'-Di-tert-butyl-2,2'-thiobisphenol | HCID 10898437 | — |
| Product | 2,4,8,10-Tetra-t-butyl-6-phenyl-dibenzo[d,g][1,3,2,6]dioxasilathiocin | HCID 123476377 | 41% |
Reaction Steps
Utilizing the procedure of Example 1, this compound is prepared from 5.3 grams (0.03 mole) dichlorophenylsilane, 13.3 grams (0.03 mole) 2,2'-thio-bis(4,6-di-t-butylphenol), and 6.1 grams (0.06 mole) triethylamine. Recrystallization from acetone gives 6.7 grams (41% yield) of white solid, mp 175°-177° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04582870 |
| Source dataset | uspto-grants-1986_04 |
| ORD ID | ord-91fbe5c7691c45768e306c6f266a5532 |
| Source note | uspto-grants-1986_04 |