HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Anthracenecarboxylic Acid → (10-Bromo-1-anthracenyl)methanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Anthracenecarboxylic Acid | HCID 150789 | — |
| Reactant | (Anthracen-1-yl)methanol | HCID 12695455 | — |
| Reactant | HCID 21276215 | HCID 21276215 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | (10-Bromo-1-anthracenyl)methanol | HCID 13375398 | — |
Reaction Steps
10-Bromo-1-anthracenecarboxylic acid made from 1-anthracenecarboxylic acid (15B) by the procedure of E. Barnett, J. W. Cook, and H. H. Grainger, Ber. 57 B, 1775 (1924), was reduced with BH3 in THF by the procedure outlined in 15C to give (10-bromo-1-anthracenyl)methanol mp 125°-127°, (EtOAc/hexane), (C, H, Br).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04803221 |
| Source dataset | uspto-grants-1989_02 |
| ORD ID | ord-f4db24597f4541fe96f0b2c49abe5d20 |
| Source note | uspto-grants-1989_02 |