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HRID1382431

反应详情

EQUATION

反应方程式

HRID 1382431 的结构方程式

REACTANTS

反应物

2
结构：CCOP(=O)(OCC)C(Cl)c1ccc(C)cc1
HCID13604830

Phosphonic acid, P-[chloro(4-methylphenyl)methyl]-, diethyl ester

C12H18ClO3P

结构：CC1(C)CCC(C)(C)c2cc(C=O)c(F)cc21
HCID23498978

未命名化合物

PRODUCTS

生成物

1
结构：Cc1ccc(C#Cc2cc3c(cc2F)C(C)(C)CCC3(C)C)cc1
HCID19786975

未命名化合物

PROCEDURE

实验过程

Using a process similar to that described in Example 13, 27.7 g (0.1 mole) of diethyl 1-chloro-(4-tolyl)-methylphosphonate, 23.4 g (0.1 mole) of 3-fluoro-2-formyl-5,6,7,8-tetrahydro-5,5,8,8-tetramethylnaphthalene and 22.5 g (0.2 mole) of potassium tert.-butylate were reacted for 1 hour to give the title compound. Recrystallization from isopropanol gave 16.4 g (51%) of product of melting point 60°-61° C.

WORKUP

后处理

  1. customwere reacted for 1 hour