HRID1382532

反应详情

EQUATION

反应方程式

REACTANTS

反应物

$结构：CCCCC(C)(C)C(=O)/C=C/[C@@H]1[C@@H](C/C=C\CCCC(=O)OC)[C@H](Cl)C[C@H]1OC1CCCCO1$

HCID13853246

未命名化合物

PRODUCTS

生成物

$结构：CCCCC(C)(C)C(=O)/C=C/[C@@H]1[C@@H](C/C=C\CCCC(=O)OC)[C@H](Cl)C[C@H]1O.CCCCC=CC(=O)OC$

HCID86742756

未命名化合物

收率 128.9%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID21877175

未命名化合物

PROCEDURE

实验过程

1 g of VIII is stirred for 24 hours at 40° C. with 25 ml of a mixture of glacial acetic acid-water-tetrahydrofuran (65/35/10). It is concentrated by evaporation in a vacuum, chromatographed on silica gel with hexane/10-50% ethyl acetate, and 720 mg of IX is obtained as oil.

WORKUP

后处理

concentrationIt is concentrated by evaporation in a vacuum
customchromatographed on silica gel with hexane/10-50% ethyl acetate