HRID1382682

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID5319562

Methyl trans-4-hydroxycinnamate

C10H10O3

HCID53869168

未命名化合物

PRODUCTS

生成物

结构：COC(=O)C=Cc1ccc(OCC(C)=CCc2c(C)c(OC)c(OC)c(OC)c2OC)cc1

HCID53641548

未命名化合物

结构：COc1c(C)c(CC=C(C)COc2ccc(C=CC(=O)O)cc2)c(OC)c(OC)c1OC

HCID53993150

未命名化合物

PROCEDURE

实验过程

Using 1,2,3,4-tetramethoxy-5-methyl-6-(4-chloro-3-methyl-2-butenyl)benzene and methyl p-hydroxycinnamate and following the procedure described above, there were obtained methyl 4-[4-(2,3,4,5-tetramethoxy-6-methylphenyl)-2-methyl-2-butenyloxy]cinnamate (Compound 11) and 4-[4-(2,3,4,5-tetramethoxy-6-methylphenyl)-2-methyl-2-butenyloxy]-cinnamic acid (Compound 12).

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-eaae1415473045d189cd5a3fa5a0d73d
来源数据集: uspto-grants-1989_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04808339
来源说明: uspto-grants-1989_02

反应 SMILES

[CH3:1][O:2][C:3]1[C:8]([CH2:9][CH:10]=[C:11]([CH3:14])[CH2:12]Cl)=[C:7]([CH3:15])[C:6]([O:16][CH3:17])=[C:5]([O:18][CH3:19])[C:4]=1[O:20][CH3:21].[CH3:22][O:23][C:24](/[CH:26]=[CH:27]/[C:28]1[CH:29]=[CH:30][C:31]([OH:34])=[CH:32][CH:33]=1)=[O:25]>>[CH3:1][O:2][C:3]1[C:4]([O:20][CH3:21])=[C:5]([O:18][CH3:19])[C:6]([O:16][CH3:17])=[C:7]([CH3:15])[C:8]=1[CH2:9][CH:10]=[C:11]([CH3:14])[CH2:12][O:34][C:31]1[CH:30]=[CH:29][C:28]([CH:27]=[CH:26][C:24]([O:23][CH3:22])=[O:25])=[CH:33][CH:32]=1.[CH3:1][O:2][C:3]1[C:4]([O:20][CH3:21])=[C:5]([O:18][CH3:19])[C:6]([O:16][CH3:17])=[C:7]([CH3:15])[C:8]=1[CH2:9][CH:10]=[C:11]([CH3:14])[CH2:12][O:34][C:31]1[CH:30]=[CH:29][C:28]([CH:27]=[CH:26][C:24]([OH:25])=[O:23])=[CH:33][CH:32]=1