HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Hydroxide → HCID 14047794, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | Methanesulfonyl chloride | HCID 31297 | — |
| Reactant | 2,6-Di-tert-butyl-4-mercaptophenol | HCID 70370 | — |
| Reactant | HCID 21273723 | HCID 21273723 | — |
| Solvent | Triethylamine | HCID 8471 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Solvent | Heptane | HCID 8900 | — |
| Product | HCID 14047794 | HCID 14047794 | 44.2% |
Reaction Steps
The procedure of Example 3 was repeated using 10.0 grams of N-(hydroxymethyl)-2-(3,5-di-tert-butyl-4-hydroxyphenylthio)succinimide, 2.33 ml of methanesulfonylchloride, 5.72 ml of triethylamine, 6.52 grams of 3,5-di-tert-butyl-4-hydroxybenzene thiol and 1.09 grams of sodium hydroxide. Flash column chromatography (SiO2, 5:1 heptane:ethylacetate) afforded 7.09 grams of product as white solid, m.p. 138°-140° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04808644 |
| Source dataset | uspto-grants-1989_02 |
| ORD ID | ord-4b79d870dcbb4577bb2ace634e38abfc |
| Source note | uspto-grants-1989_02 |