HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl 4-(mercaptomethyl)-1,3-oxathiolane-2,2-dipropanoate → Diethyl 4-[[[4-[(5,6,7,8-tetrahydro-1-naphthalenyl)oxy]butyl]thio]methyl]-1,3-oxathiolane-2,2-dipropanoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl 4-(mercaptomethyl)-1,3-oxathiolane-2,2-dipropanoate | HCID 14405886 | — |
| Reactant | 5-(4-Bromobutoxy)-1,2,3,4-tetrahydronaphthalene | HCID 14405945 | — |
| Product | Diethyl 4-[[[4-[(5,6,7,8-tetrahydro-1-naphthalenyl)oxy]butyl]thio]methyl]-1,3-oxathiolane-2,2-dipropanoate | HCID 14405894 | — |
Reaction Steps
The title compound was prepared according to the procedure of Example 2 using the mercaptan produced in Example 1 (2.0 g, 0.006 mol) and the bromide produced in Example 7 (1.7 g, 0.006 mol). The crude product was chromatographed on silica gel using 20% ethyl acetate/hexane as eluent to give 2.5 g (77%) of the product as an oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04808729 |
| Source dataset | uspto-grants-1989_02 |
| ORD ID | ord-fd89c263b93a4c99a2fb2f2a97202bb5 |
| Source note | uspto-grants-1989_02 |