tert-Butyldimethylsilyl chloride → HCID 86742777, compound

Participants

Reaction Steps

By the procedure of Example 5 [3aR-[3a alpha,4alpha, (1E,3R*),5beta,6a alpha]]-4-[3-(1-methylcyclopentyl)-3-hydroxy-1-propenyl]hexahydro-5-hydroxy-2H-cyclopenta[b]furan-2-one was reacted with t-butyldimethylsilyl chloride to yield [3aR-[3a alpha,4alpha(1E,3R*),5 beta,6a alpha]]-4-[3-(1-methylcyclopentyl)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-propenyl]-5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-hexahydro-2H-cyclopenta[b]furan-2-one.

Provenance & Evidence