HCID 86742781, compound → HCID 86739807, compound

HRID 1383199Notes

Reaction equation

HRID 1383199 reaction equation
[C:1]([C@@H:3]([OH:17])[C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([O:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)[CH:5]=1)#[N:2].[CH3:18][C:19]1([CH3:32])[CH:21](/[CH:22]=[C:23](\[Cl:28])/[C:24](=[O:27])[O:25][CH3:26])[CH:20]1[C:29](O)=[O:30]>C1C=CC=CC=1>[CH3:18][C:19]1([CH3:32])[C@@H:21](/[CH:22]=[C:23](\[Cl:28])/[C:24](=[O:27])[O:25][CH3:26])[C@H:20]1[C:29]([O:17][C@H:3]([C:1]#[N:2])[C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([O:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)[CH:5]=1)=[O:30]

Participants

3

Reactant 1

HCID 86742781HCID 86742781, compound

Product 1

HCID 86739807HCID 86739807, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

Using the procedure of Example 1, (1R, cis) 2,2-dimethyl-3(Z)-[2-chloro-3-oxo-3-methoxy-propenyl]-cyclopropane-1-carboxylic acid (S)α-cyano-3-phenoxy-benzyl alcohol were reacted to obtain (S)α-cyano-3-phenoxy-benzyl (1R,cis) 2,2-dimethyl-3(Z)-[2-chloro-3-oxo-3-methoxy-propenyl]-cyclopropane-1-carboxylate with a specific rotation of [α]D20 =+62.5°±1.5° (c=1% in benzene).

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-36acc37c16194f41a67db830b747b183
Source dataset
uspto-grants-1989_02
Patent number
US04808749

Reaction notes

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