Dimethylamine → HCID 18343913, compound

HRID 1383244Notes

Reaction equation

HRID 1383244 reaction equation
[OH:1][N:2]1[C:7]([CH3:9])([CH3:8])[CH2:6][CH:5]([O:10][CH2:11][CH:12]2[O:14][CH2:13]2)[CH2:4][C:3]1([CH3:16])[CH3:15].[CH3:17][NH:18][CH3:19]>O>[OH:1][N:2]1[C:7]([CH3:9])([CH3:8])[CH2:6][CH:5]([O:10][CH2:11][CH:12]([OH:14])[CH2:13][N:18]([CH3:19])[CH3:17])[CH2:4][C:3]1([CH3:16])[CH3:15]

Participants

4

Reactant 2

HCID 674DimethylamineHCID 3662321HCID 3662321, compound

Product 1

HCID 18343913HCID 18343913, compoundYield 82.8%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture of 10.0 g (0.044 mol) of 1-oxyl-2,2,6,6-tetramethyl-4-glycidyloxypiperidine and 10 mL of 40% (ca. 0.091 mol) of dimethylamine (w/w) is dissolved in 100 mL of water and then stirred for 16 hours at ambient temperature. Water is then removed by vacuum distillation to leave 10 g of the title compound as a red oil.

Workup

  1. customWater is then removed by vacuum distillation

Sources & evidence

ORD record
ord-ead8281f4b154b71b1fcefe1762694b0
Source dataset
uspto-grants-2001_07
Patent number
US06254724B1

Reaction notes

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