Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | HCID 86757096 | HCID 86757096 | — |
| Solvent | N-methyl-2-pyrrolidone | HCID 13387 | — |
| Product | 223104-08-3 | HCID 6515677 | 53% |
Reaction Steps
25 g of potassium carbonate were suspended in 300 ml of N-methyl pyrrolidone. 30 g (0.09 mol) of crude 6Z-16-bromohexadec-6-enoic acid in 200 ml of N-methyl- pyrrolidone were added dropwise while stirring at 110-115° C. within 10 hours. After usual work up 18 g of crude product were obtained, and after chromatography 12 g (53%) of Z-oxacycloheptadec-7-en-2-one were obtained having the following characteristics: Z/E=93/7;
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06255276B1 |
|---|
| Source dataset | uspto-grants-2001_07 |
|---|
| ORD ID | ord-dcf6d2501f0e499ab4b2d2766d1e0ee5 |
|---|
| Source note | uspto-grants-2001_07 |
|---|
