HuagongsheHuagongshe Chemistry Print Report · For research reference only
Terephthalic Acid → HCID 54448556, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Terephthalic Acid | HCID 7489 | — |
| Reactant | benzyl (2R)-pyrrolidine-2-carboxylate hydrochloride | HCID 22827650 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | HCID 54448556 | HCID 54448556 | 72% |
Reaction Steps
Using General Procedure A with 5.8 g (24.0 mmol) D-Proline benzyl ester hydrochloride and 2.0 g (12.0 mmol) benzene-1,4-dioic acid afforded, after flash chromatography (EtOAc), 4.66 g (72%) of the title compound as a yellow oil. MS m/e (%): 558 (M+NH4+, 100), 541 (M+H+, 95).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06262089B1 |
| Source dataset | uspto-grants-2001_07 |
| ORD ID | ord-aa7f1c789a4f4ee39b5c2c4c1f4a7a2f |
| Source note | uspto-grants-2001_07 |