HuagongsheHuagongshe Chemistry Print Report · For research reference only
Chlorotrimethylsilane → Silane, trimethyl[[2-methyl-1-(1-methylethyl)-1-propenyl]oxy]-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Chlorotrimethylsilane | HCID 6397 | — |
| Reactant | 2,4-Dimethyl-3-pentanone | HCID 11271 | — |
| Product | Silane, trimethyl[[2-methyl-1-(1-methylethyl)-1-propenyl]oxy]- | HCID 11095327 | — |
Reaction Steps
Reaction between 2,4-dimethyl-3-pentanone (1.2.4.3), trimethylsilyl chloride, and base gave 2,4-dimethyl-3-trimethysilyloxy-2-pentene (1.2.4.4) which was reacted with 1-fluoropyridinium triflate (1.2.4.5) to form 2,4-dimethyl-2-fluoro-3-pentanone (1.2.4.6). This product was reacted with (CH3)3S(O)+I− to form the title compound (1.2.4.2).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06264966B1 |
| Source dataset | uspto-grants-2001_07 |
| ORD ID | ord-233ce65245b8496fb0638fce8343e3dd |
| Source note | uspto-grants-2001_07 |