化工社化工社 化学情報印刷レポート · 研究参考用
Tetramethylammonium hydroxide → Tetramethylammonium pentafluorobenzenesulfonate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Tetramethylammonium hydroxide | HCID 60966 | — |
| 反応物 | 2,3,4,5,6-Pentafluorobenzenesulfonyl chloride | HCID 70026 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | Tetramethylammonium pentafluorobenzenesulfonate | HCID 21964803 | — |
反応手順
In 100 ml of methanol, 25 g of pentafluorobenzenesulfonyl chloride was dissolved under ice cooling, and 100 g of a 25% aqueous solution of tetramethylammonium hydroxide was slowly added thereto. Stirring at room temperature for 3 hours provided a solution of tetramethylammonium pentafluorobenzenesulfonate. This solution was used for salt exchange with a sulfonium salt and an iodonium salt.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06265135B1 |
| 出典データセット | uspto-grants-2001_07 |
| ORD ID | ord-85de58f66ddc43c29b946c8b4aa54e18 |
| 出典メモ | uspto-grants-2001_07 |