HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → 7,8,9,10-Tetrahydro-1,3-dihydroxy-7-phenyl-6H-dibenzo[b,d]pyran-6-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Phloroglucinol | HCID 359 | — |
| Reactant | HCID 10105963 | HCID 10105963 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 7,8,9,10-Tetrahydro-1,3-dihydroxy-7-phenyl-6H-dibenzo[b,d]pyran-6-one | HCID 23500383 | — |
Reaction Steps
A solution of phloroglucinol (0.7 g) and 2-ethoxycarbonyl-3-phenylcyclohexanone (1.5 g) in ethanol was treated with dry HCl as described in example 1a. The product was first recrystallized from ethanol-water (1:1) and then triturated with ether. Yield 0.61 g.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06265421B1 |
| Source dataset | uspto-grants-2001_07 |
| ORD ID | ord-6cbe00efa9ce423ab4d75985712dd137 |
| Source note | uspto-grants-2001_07 |