HRID1388577

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CCCCCCCCc1ccc(Nc2ccc(CCCCCCCC)cc2)cc1

HCID7569

4,4'-Dioctyldiphenylamine

C28H43N

结构：CCn1c(C)c(C(=O)c2ccccc2C(=O)O)c2ccccc21

HCID3084978

Benzoic acid, 2-[(1-ethyl-2-methyl-1H-indol-3-yl)carbonyl]-

C19H17NO3

PRODUCTS

生成物

结构：CCCCCCCCc1ccc(N(c2ccc(CCCCCCCC)cc2)C2(c3c(C)n(CC)c4ccccc34)OC(=O)c3ccccc32)cc1

HCID20471342

未命名化合物

PROCEDURE

实验过程

Following a procedure similar to that described in Example 2B but employing 10.0 g of 2-(1-ethyl-2-methyl-3-indolylcarbonyl)benzoic acid and 13.0 g of 4,4'-dioctyldiphenylamine there was obtained a quantitive yield of 3-(1-ethyl-2-methyl-3-indolyl)-3-[N,N-bis-(4-octylphenyl)amino]phthalide, m.p. 106°-108° C. A toluene solution of the product contacted with acidic clay or phenolic resin developed a yellow-colored image.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-d3cdd6ef91cb492a8c006d4c6ae61bd9
来源数据集: uspto-grants-1984_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04431819
来源说明: uspto-grants-1984_02

反应 SMILES

[CH2:1]([N:3]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[C:5]([C:12]([C:14]2[CH:22]=[CH:21][CH:20]=[CH:19][C:15]=2[C:16](O)=[O:17])=[O:13])=[C:4]1[CH3:23])[CH3:2].[CH3:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][C:32]1[CH:37]=[CH:36][C:35]([NH:38][C:39]2[CH:44]=[CH:43][C:42]([CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH3:52])=[CH:41][CH:40]=2)=[CH:34][CH:33]=1>>[CH2:1]([N:3]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[C:5]([C:12]2([N:38]([C:39]3[CH:40]=[CH:41][C:42]([CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH3:52])=[CH:43][CH:44]=3)[C:35]3[CH:34]=[CH:33][C:32]([CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH3:24])=[CH:37][CH:36]=3)[C:14]3[C:15](=[CH:19][CH:20]=[CH:21][CH:22]=3)[C:16](=[O:17])[O:13]2)=[C:4]1[CH3:23])[CH3:2]