Sodium Hydroxide → HCID 70495974, compound

HRID 1388642Notes

Reaction equation

HRID 1388642 reaction equation
C([O:3][C:4](=[O:30])[C@H:5]([CH2:19][C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][C:21]=1[O:26]C(=O)C)[NH:6][C:7](=[O:18])[CH2:8][NH:9][C:10]([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)=[O:11])C.[OH-].[Na+]>CO>[OH:26][C:21]1[CH:22]=[CH:23][CH:24]=[CH:25][C:20]=1[CH2:19][C@@H:5]([C:4]([OH:30])=[O:3])[NH:6][C:7](=[O:18])[CH2:8][NH:9][C:10]([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)=[O:11]

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 70495611HCID 70495611, compound

Product 1

HCID 70495974HCID 70495974, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

7.69 g (0.02 M) of o-acetoxyhippuryl-L-phenylalanine ethyl ester was dissolved in 50 ml of methanol and to this solution was added 70 ml of a 0.1 N aqueous solution of NaOH, and then this solution was treated by repeating the same procedure as Procedure 1 supra to obtain o-hydroxyhippuryl-L-phenylalanine.

Workup

  1. additionthis solution was treated

Sources & evidence

ORD record
ord-161f069d70f54686ae917207773f65ca
Source dataset
uspto-grants-1984_02
Patent number
US04432896

Reaction notes

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