HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylformamide → (E)-1-(4-tert-butylphenyl)-1-cyclopropyl-N-[(2-methyl-3-phenylphenyl)methoxy]methanimine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylformamide | HCID 6228 | — |
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | (NE)-N-[(4-tert-butylphenyl)-cyclopropylmethylidene]hydroxylamine | HCID 13282518 | — |
| Reactant | 3-(Chloromethyl)-2-methyl-1,1'-biphenyl | HCID 13282519 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | (E)-1-(4-tert-butylphenyl)-1-cyclopropyl-N-[(2-methyl-3-phenylphenyl)methoxy]methanimine | HCID 13282542 | — |
Reaction Steps
In a manner similar to Example 2, the reaction of 0.75 g (0.0034 mole) of (E)-(4-t-butylphenyl)(cyclopropyl)methanone oxime with 0.2 g (0.008 mole) of sodium hydride and 0.74 g (0.0034 mole) of 3-chloromethyl-2-methyl[1,1'-biphenyl] in 25 ml of a 20% solution of N,N-dimethylformamide in toluene produced (E)-(4-t-butylphenyl)(cyclopropyl)methanone O-[(2-methyl[1,1'-biphenyl]-3-yl)methyl]oxime as an oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04434182 |
| Source dataset | uspto-grants-1984_02 |
| ORD ID | ord-6e1d7188291547ceaa947026491a5f39 |
| Source note | uspto-grants-1984_02 |