HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phthalide → 1(3H)-Isobenzofuranone, 3-bromo-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phthalide | HCID 6885 | — |
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | 1(3H)-Isobenzofuranone, 3-bromo- | HCID 96218 | 100.7% |
Reaction Steps
A mixture of 1-isobenzofuranone (150 g) and N-bromosuccinimide (199.05 g) in carbon tetrachloride (3000 ml) is irradiated with a 500 W photospot lamp for 3 hr, cooled and filtered. The filtrate is evaporated to give 3-bromo-1-isobenzofuranone (240 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04244966 |
| Source dataset | uspto-grants-1981_01 |
| ORD ID | ord-3e589d6af5b84f94823cb6d22175a448 |
| Source note | uspto-grants-1981_01 |