3-Thienylsulfinylacetic acid → HCID 178521535, compound

HRID 1389596Notes

Reaction equation

HRID 1389596 reaction equation
[S:1]1[CH:5]=[CH:4][C:3]([S:6]([CH2:8][C:9]([OH:11])=O)=[O:7])=[CH:2]1.[NH2:12][CH:13]1[C:30](=[O:31])[N:15]2[C:16]([C:27]([OH:29])=[O:28])=[C:17]([CH2:20][S:21][C:22]3[NH:26][N:25]=[N:24][CH:23]=3)[CH2:18][S:19][C@H:14]12>>[S:1]1[CH:5]=[CH:4][C:3]([S:6]([CH2:8][C:9]([NH:12][CH:13]2[C:30](=[O:31])[N:15]3[C:16]([C:27]([OH:29])=[O:28])=[C:17]([CH2:20][S:21][C:22]4[NH:26][N:25]=[N:24][CH:23]=4)[CH2:18][S:19][C@H:14]23)=[O:11])=[O:7])=[CH:2]1

Participants

3

Reactant 2

HCID 202972313-Thienylsulfinylacetic acidHCID 178508102HCID 178508102, compound

Product 1

HCID 178521535HCID 178521535, compound

Procedure

380 mg. of 3-thienylsulfinylacetic acid of the R form and 7-amino-3-(1H-1,2,3-triazol-5-ylthiomethyl)-3-cephem-4-carboxylic acid were reacted in the same manner as described in Example 28 and 369 mg. of 7-(3-thienylsulfinylacetamido)-3-(1H-1,2,3-triazol-5-ylthiomethyl)-3-cephem-4-carboxylic acid of the R form were obtained.

Sources & evidence

ORD record
ord-07486f8f2257456a8dfaa7ba60e56533
Source dataset
uspto-grants-1981_01
Patent number
US04245107

Reaction notes

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