HCID 53634662, compound → HCID 44279631, compound

HRID 1389691Notes

Reaction equation

HRID 1389691 reaction equation
[C:1]1([O:7][C:8]([C:10]2[CH:15]=[C:14]([NH:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH:13]=[C:12]([C:25]([O:27][C:28]3[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=3)=[O:26])[C:11]=2[C:34]([O:36][C:37]2[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=2)=[O:35])=[O:9])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C1(OC([C:52]2[CH:57]=[C:56](NCCCCCCCCC)[CH:55]=[C:54]([C:68](OC3C=CC=CC=3)=O)[C:53]=2[C:77](OC2C=CC=CC=2)=O)=O)C=CC=CC=1.C1(OC(C2C=C(NCCCCCCCCCC)C=C(C(OC3C=CC=CC=3)=O)C=2C(OC2C=CC=CC=2)=O)=O)C=CC=CC=1.C1(OC(C2C=C(NCCCCCCCCCCC)C=C(C(OC3C=CC=CC=3)=O)C=2C(OC2C=CC=CC=2)=O)=O)C=CC=CC=1.C1(OC(C2C=C(NC(C)CCCCCCCCCC)C=C(C(OC3C=CC=CC=3)=O)C=2C(OC2C=CC=CC=2)=O)=O)C=CC=CC=1.C1(OC(C2C=C(NCCCCCCCCCCCCC)C=C(C(OC3C=CC=CC=3)=O)C=2C(OC2C=CC=CC=2)=O)=O)C=CC=CC=1.C1(OC(C2C=C(NCCCCCCCCCCCCCC)C=C(C(OC3C=CC=CC=3)=O)C=2C(OC2C=CC=CC=2)=O)=O)C=CC=CC=1.C1(OC(C2C=C(NCCCCCCCCCCCCCCC)C=C(C(OC3C=CC=CC=3)=O)C=2C(OC2C=CC=CC=2)=O)=O)C=CC=CC=1.C1(OC(C2C=C(NCCCCCCCCCCCCCC(C)C)C=C(C(OC3C=CC=CC=3)=O)C=2C(OC2C=CC=CC=2)=O)=O)C=CC=CC=1.C1(OC(C2C=C(NCCCCCCCCCCCCCCCCC)C=C(C(OC3C=CC=CC=3)=O)C=2C(OC2C=CC=CC=2)=O)=O)C=CC=CC=1.C1(OC(C2C=C(NCCCCCCCCCCCCCCCCCC)C=C(C(OC3C=CC=CC=3)=O)C=2C(OC2C=CC=CC=2)=O)=O)C=CC=CC=1.C1(OC(C2C=C(NCCCCCCCCCCCCCCCCCCC)C=C(C(OC3C=CC=CC=3)=O)C=2C(OC2C=CC=CC=2)=O)=O)C=CC=CC=1>>[C:1]1([O:7][C:8]([C:10]2[CH:15]=[C:14]([NH:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:77][CH2:53][CH2:52][CH2:57][CH2:56][CH2:55][CH2:54][CH3:68])[CH:13]=[C:12]([C:25]([O:27][C:28]3[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=3)=[O:26])[C:11]=2[C:34]([O:36][C:37]2[CH:38]=[CH:39][CH:40]=[CH:41][CH:42]=2)=[O:35])=[O:9])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

13

Reactant 12

HCID 53634662HCID 53634662, compoundHCID 53742839HCID 53742839, compoundHCID 53743569HCID 53743569, compoundHCID 53938865HCID 53938865, compoundHCID 54028076HCID 54028076, compoundHCID 54293588HCID 54293588, compoundHCID 54342768HCID 54342768, compoundHCID 54400520HCID 54400520, compoundHCID 54412312HCID 54412312, compoundHCID 54455065HCID 54455065, compoundHCID 54505723HCID 54505723, compoundHCID 54533399HCID 54533399, compound

Product 1

HCID 44279631HCID 44279631, compound

Procedure

Similarly, 1-bromooctane, 1-bromononane, 1-bromodecane, 1-bromoundecane, 2-bromododecane, 1-bromododecane, 1-bromotridecane, 1-bromotetradecane, 1-bromopentadecane, 1-bromo-14-methylpentadecane, 1-bromoheptadecane, 1-bromooctadecane, and 1-bromononadecane, give respectively, 5-octylamino-1,2,3-benzenetricarboxylic acid triphenyl ester, 5-nonylamino-1,2,3-benzenetricarboxylic acid triphenyl ester, 5-decylamino-1,2,3-benzenetricarboxylic acid triphenyl ester, 5-undecylamino-1,2,3-benzenetricarboxylic acid triphenyl ester, 5-(1-methylundecyl)amino-1,2,3-benzenetricarboxylic acid triphenyl ester, 5-dodecyclamino-1,2,3-benzenetricarboxylic acid triphenyl ester, 5-tridecylamino-1,2,3-benzenetricarboxylic acid triphenyl ester, 5-tetradecylamino-1,2,3-benzenetricarboxylic acid triphenyl ester, 5-pentadecylamino-1,2,3-benzenetricarboxylic acid triphenyl ester, 5-(14-methylpentadecyl)amino-1,2,3-benzenetricarboxylic acid triphenyl ester, 5-heptadecylamino-1,2,3-benzenetricarboxylic acid triphenyl ester, 5-octadecylamino-1,2,3-benzenetricarboxylic acid triphenyl ester, and 5-nonadecylamino-1,2,3-benzenetricarboxylic acid triphenyl ester.

Sources & evidence

ORD record
ord-1bd6423dfe7e4d82b3e640198a50cadb
Source dataset
uspto-grants-1981_01
Patent number
US04245120

Reaction notes

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