HCID 20297295, compound → HCID 20297336, compound

HRID 1389692Notes

Reaction equation

HRID 1389692 reaction equation
[CH2:1]([NH:9][C:10]1[CH:11]=[C:12]([C:22]([OH:24])=[O:23])[C:13]([C:19]([OH:21])=[O:20])=[C:14]([C:16]([OH:18])=[O:17])[CH:15]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[CH2:25](NC1C=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C=1)[CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32]C.C(NC1C=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C=1)CCCCCCCCC.C(NC1C=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C=1)CCCCCCCCCC.CC(NC1C=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C=1)CCCCCCCCCC.C(NC1C=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C=1)CCCCCCCCCCC.C(NC1C=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C=1)CCCCCCCCCCCC.C(NC1C=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C=1)CCCCCCCCCCCCC.C(NC1C=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C=1)CCCCCCCCCCCCCC.CC(C)CCCCCCCCCCCCCNC1C=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C=1.C(NC1C=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C=1)CCCCCCCCCCCCCCCC.C(NC1C=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C=1)CCCCCCCCCCCCCCCCC.C(NC1C=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C=1)CCCCCCCCCCCCCCCCCC>>[CH2:1]([NH:9][C:10]1[CH:15]=[C:14]([C:16]([OH:18])=[O:17])[C:13]([C:19]([OH:21])=[O:20])=[C:12]([C:22]([OH:24])=[O:23])[CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH3:32]

Participants

14

Reactant 13

HCID 20297295HCID 20297295, compoundHCID 20297306HCID 20297306, compoundHCID 20297310HCID 20297310, compoundHCID 20297312HCID 20297312, compoundHCID 20297316HCID 20297316, compoundHCID 20297322HCID 20297322, compoundHCID 20297334HCID 20297334, compoundHCID 20297340HCID 20297340, compoundHCID 20297353HCID 20297353, compoundHCID 20297354HCID 20297354, compoundHCID 20297355HCID 20297355, compoundHCID 20297358HCID 20297358, compoundHCID 20297361HCID 20297361, compound

Product 1

HCID 20297336HCID 20297336, compound

Procedure

Similarly, the 5-alkylamino-1,2,3-benzenetricarboxylic acid triphenyl esters described in Example 5 give, respectively, 5-octylamino-1,2,3-benzenetricarboxylic acid, 5-nonylamino-1,2,3-benzenetricarboxylic acid, 5-decylamino-1,2,3-benzenetricarboxylic acid, 5-undecylamino-1,2,3-benzenetricarboxylic acid, 5-(1-methylundecyl)amino-1,2,3-benzenetricarboxylic acid, 5-dodecylamino-1,2,3-benzenetricarboxylic acid, 5-tridecylamino-1,2,3-benzenetricarboxylic acid, 5-tetradecylamino-1,2,3-benzenetricarboxylic acid, 5-pentadecylamino-1,2,3-benzenetricarboxylic acid, 5-(14-methylpentadecyl)amino-1,2,3-benzenetricarboxylic acid, 5-heptadecylamino-1,2,3-benzenetricarboxylic acid, 5-octadecylamino-1,2,3-benzenetricarboxylic acid, and 5-nonadecylamino-1,2,3-benzenetricarboxylic acid.

Workup

  1. customgive

Sources & evidence

ORD record
ord-41380712d2e04ca38045ec578e8b21ae
Source dataset
uspto-grants-1981_01
Patent number
US04245120

Reaction notes

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