Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 2-Methoxyethanol | HCID 8019 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | Benzenesulfonic acid, 2-chloro-5-nitro-, sodium salt (1:1) | HCID 70350 | — |
| Catalyst | HCID 178418406 | HCID 178418406 | — |
| Solvent | Water | HCID 962 | — |
| Product | CID 101686797 | HCID 101686797 | — |
Reaction Steps
A mixture of 5.2 g of sodium 2-chloro-5-nitrobenzenesulfonate, 0.6 g of manganese dioxide, 15 ml of 2-methoxyethanol, 1 ml of water and 0.95 g of sodium hydroxide was stirred at 75° C. for 40 minutes. After cooling (to 25° C.), the insoluble materials were removed by filtration and the filtrate was poured into 100 ml of isopropyl alcohol. The crystals thus-precipitated were recovered by filtration to obtain 4.8 g of sodium 2-(2-methoxyethoxy)-5-nitrobenzenesulfonate. Melting Point: 238° to 239° C. The infrared absorption spectrum of this compound was the same as that of the compound obtained in Method 1 above.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04246414 |
|---|
| Source dataset | uspto-grants-1981_01 |
|---|
| ORD ID | ord-d55b4b2b38e2414f868f4d96da8cda15 |
|---|
| Source note | uspto-grants-1981_01 |
|---|
