Propargyl bromide → HCID 54190426, compound

HRID 1390388Notes

Reaction equation

[CH3:1][C:2]([CH2:15][CH2:16][CH:17]=[C:18]([CH3:20])[CH3:19])=[CH:3][CH2:4][O:5][C:6]1[CH:14]=[CH:13][C:9]([C:10]([OH:12])=[O:11])=[CH:8][CH:7]=1.[CH2:21](Br)[C:22]#[CH:23]>>[CH2:23]([O:11][C:10](=[O:12])[C:9]1[CH:8]=[CH:7][C:6]([O:5][CH2:4][CH:3]=[C:2]([CH3:1])[CH2:15][CH2:16][CH:17]=[C:18]([CH3:20])[CH3:19])=[CH:14][CH:13]=1)[C:22]#[CH:21]

Participants

Reactant 2

HCID 7842Propargyl bromide

HCID 54274018HCID 54274018, compound

Product 1

HCID 54190426HCID 54190426, compound

Procedure

By utilizing the procedure of Example 8, by reacting p-[(3,7-dimethyl-2,6-octadienyl)oxy]benzoic acid with propargyl bromide, there is obtained p-[(3,7-dimethyl-2,6-octadienyl)oxy]benzoic acid propargyl ester; B.P. 135°-137° C./0.01 mmHg.

Sources & evidence

ORD record: ord-82ba764c955748ff8bdefec8944e2c54
Source dataset: uspto-grants-1979_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04138579

Reaction notes

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