Propargyl bromide → HCID 53960113, compound

HRID 1390394Notes

Reaction equation

[CH2:1]([CH:3]([O:11][C:12]1[CH:20]=[CH:19][C:15]([C:16]([OH:18])=[O:17])=[CH:14][CH:13]=1)[CH2:4][CH2:5][CH:6]=[C:7]([CH3:10])[CH2:8][CH3:9])[CH3:2].[CH2:21](Br)[C:22]#[CH:23]>>[CH2:23]([O:17][C:16](=[O:18])[C:15]1[CH:19]=[CH:20][C:12]([O:11][CH:3]([CH2:1][CH3:2])[CH2:4][CH2:5][CH:6]=[C:7]([CH3:10])[CH2:8][CH3:9])=[CH:13][CH:14]=1)[C:22]#[CH:21]

Participants

Reactant 2

HCID 7842Propargyl bromide

HCID 53693906HCID 53693906, compound

Product 1

HCID 53960113HCID 53960113, compound

Procedure

By utilizing the procedure of Example 8, by reacting p-[(1-ethyl-5-methyl-4-heptenyl)oxy]benzoic acid with propargyl bromide, there is obtained p-[(1-ethyl-5-methyl-4-heptenyl)oxy]benzoic acid propargyl ester; nD21 = 1.5200.

Sources & evidence

ORD record: ord-75770c8f29ce413e802ebf1efb465fa3
Source dataset: uspto-grants-1979_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04138579

Reaction notes

Loading…