Sodium Perborate → HCID 21332693, compound

HRID 1390556Notes

Reaction equation

HRID 1390556 reaction equation
[NH2:1][C:2]1[CH:7]=[CH:6][C:5]([Br:8])=[CH:4][C:3]=1[C:9]1[CH:14]=[C:13]([Br:15])[CH:12]=[CH:11][C:10]=1[NH2:16].B(O[O-])=O.[Na+]>>[Br:15][C:13]1[CH:12]=[CH:11][C:10]2[N:16]=[N:1][C:2]3[CH:7]=[CH:6][C:5]([Br:8])=[CH:4][C:3]=3[C:9]=2[CH:14]=1

Participants

3

Reactant 2

HCID 517072Sodium PerborateHCID 21332651HCID 21332651, compound

Product 1

HCID 21332693HCID 21332693, compound

Procedure

The 2,9-dibromo-benzo-[c]-cinnoline is prepared from the 2,2'-diamino-5,5'-dibromo-biphenyl described by Le Fevre (J. Chem. Soc. 1929, 736) according to the oxidation method with sodium perborate of J. F. Corbett, P. F. Holt (J. Chem. Soc. 1961, 3698).

Sources & evidence

ORD record
ord-b60d431afaa04a6cb99d0a64da8912af
Source dataset
uspto-grants-1979_02
Patent number
US04139530

Reaction notes

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