huagongshe.com
HRID1390744

反应详情

EQUATION

反应方程式

HRID 1390744 的结构方程式

REACTANTS

反应物

3
结构：CC1=C2CC[C@@H]3[C@H](CC[C@]4(C)[C@@H](O)CC[C@@H]34)[C@@]2(CO)CCC1=O
HCID53641160

未命名化合物

结构：CC1=C2C[C@@H](C)[C@@H]3[C@H](CC[C@]4(C)[C@@H](O)CC[C@@H]34)[C@@]2(CO)CCC1=O
HCID53851300

未命名化合物

结构：CC1=C2CC[C@@H]3[C@H](CC[C@]4(C)C(=O)CC[C@@H]34)[C@@]2(CO)[C@@H](C)CC1=O
HCID70585456

未命名化合物

PRODUCTS

生成物

3
结构：C[C@@H]1C(=O)C[C@H](C)[C@@]2(CO)C1=CC[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]12
HCID70605333

未命名化合物

结构：C[C@@H]1C(=O)CC[C@@]2(CO)C1=CC[C@@H]1[C@@H]2CC[C@]2(C)[C@@H](O)CC[C@@H]12
HCID70605756

未命名化合物

结构：C[C@@H]1C(=O)CC[C@@]2(CO)C1=C[C@@H](C)[C@@H]1[C@@H]2CC[C@]2(C)[C@@H](O)CC[C@@H]12
HCID70605854

未命名化合物

PROCEDURE

实验过程

Substituting 17β,19-dihydroxy-4-methyl-4-androsten-3-one, 19-hydroxy-1α,4-dimethyl-4-androstene-3,17-dione, 17β,19-dihydroxy-4,7α-dimethyl-4-androsten-3-one, 4-methyl-17β,19-di(2'-tetrahydropyranyloxy)-4-androsten-3-one and 1α,4-dimethyl-19-(2'-tetrahydropyranyloxy)-4-androstene-3,17-dione for the 17β,19-dihydroxy-4,6α,17α-trimethyl-4-androsten-3-one above results in the formation of 17β,19-dihydroxy-4α-methyl-5-androsten-3-one, 19-hydroxy-1α,4α-dimethyl-5-androstene-3,17-dione, 17β,19-dihydroxy-4α,7α-dimethyl-5-androsten-3-one, 4α-methyl-17β,19-di(2'-tetrahydropyranyloxy)-5-androsten-3-one and 1α,4α-dimethyl-19-(2'-tetrahydropyranyloxy)-5-androstene-3,17-dione, respectively.