HRID1390787

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID175

Acetate

C2H3O2-

结构：CC(=O)O.CC(C)(C)[Si](C)(C)OC1CC[C@@]2(CO)C(=CC[C@@H]3[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]32)C1

HCID131711428

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)[Si](C)(C)OC1CC[C@@]2(CO)C(=CC[C@@H]3[C@@H]2CC[C@]2(C)[C@@H](O)CC[C@@H]32)C1

HCID70605173

未命名化合物

PROCEDURE

实验过程

Substituting 3-t-butyldimethylsiloxy-19-hydroxy-5-androsten-17-one acetate and 19-hydroxy-3β-(4'-tetrahydropyranyloxy)-5-androsten-17-one acetate for the 19-hydroxy-3β-(2'-tetrahydropyranyloxy)-5-androsten-17-one, acetate above results in the preparation of 3-t-butyldimethylsiloxy-5-androsten-17β,19-diol and 3β-(4'-tetrahydropyranyloxy)-5-androstene-17β,19-diol, respectively.