HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Anhydride → HCID 54524075, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Anhydride | HCID 7918 | — |
| Reactant | Methyl 2-nitroacetate | HCID 17206 | — |
| Reactant | HCID 3557290 | HCID 3557290 | — |
| Product | HCID 54524075 | HCID 54524075 | 81% |
Reaction Steps
A mixture of 63.0 g (0.29 mol) of the compound of Example 14 and 35.7 g (0.30 mol) of methyl nitroacetate in 600 ml. of acetic anhydride was heated at 85° for 2 hours. The resulting product was worked up and recrystallized from benzene-DMF (2:1) affording 74.9 g (81%) of product as red orange crystals, m.p. 211-214°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04140697 |
| Source dataset | uspto-grants-1979_02 |
| ORD ID | ord-2268d2789c084842869b47aecc5a5aef |
| Source note | uspto-grants-1979_02 |