Sulfuryl chloride → HCID 21670873, compound

HRID 1390858Notes

Reaction equation

HRID 1390858 reaction equation
S(Cl)([Cl:4])(=O)=O.[CH3:6][O:7][C:8]1([O:16][CH3:17])[CH2:13][CH2:12][CH2:11][CH2:10][C:9]1=[N:14][OH:15]>C(Cl)Cl>[Cl:4][CH:13]1[CH2:12][CH2:11][CH2:10][C:9](=[N:14][OH:15])[C:8]1([O:7][CH3:6])[O:16][CH3:17]

Participants

4

Reactant 2

HCID 24648Sulfuryl chlorideHCID 71365596N-(2,2-Dimethoxycyclohexylidene)hydroxylamine

Product 1

HCID 21670873HCID 21670873, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent2×

Procedure

A solution of 1.66 parts sulfuryl chloride dissolved in 8 parts dry methylene chloride was added under a dry nitrogen atmosphere over a 15-minute period to a stirred solution of 1.73 parts 2,2-dimethoxycyclohexanone oxime dissolved in about 8 parts dry methylene chloride. After the addition was completed, the contents were stirred for an additional hour and then treated by the procedure in Example 1 to yield 1.5 parts of 3-chloro-2,2-dimethoxycyclohexanone oxime.

Workup

  1. additionAfter the addition
  2. additiontreated by the procedure in Example 1

Sources & evidence

ORD record
ord-c7241a487e604a29a85abfacc6acf955
Source dataset
uspto-grants-1979_02
Patent number
US04140717

Reaction notes

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