Chlorine → HCID 86736351, compound

HRID 1390859Notes

Reaction equation

HRID 1390859 reaction equation
[CH3:1][O:2][C:3]1([O:13][CH3:14])[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][C:4]1=[N:11][OH:12].[Cl:15]Cl>C(Cl)Cl>[Cl:15][CH:10]1[CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][C:4](=[N:11][OH:12])[C:3]1([O:2][CH3:1])[O:13][CH3:14]

Participants

4

Reactant 2

HCID 24526ChlorineHCID 71371084N-(2,2-Dimethoxycyclooctylidene)hydroxylamine

Product 1

HCID 86736351HCID 86736351, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Following the general procedure of Example 1, to a solution of 5.025 parts of 2,2-dimethoxycyclooctanone oxime in 40 parts dry methylene chloride at about 35° C., was added 1.78 parts elemental chlorine over about 3/4 of an hour. The contents were stirred at 25° to 30° C. for about 21/2 hours after the addition. The contents were then treated according to the procedure of Example 1 to yield 5.3 parts of product 3-chloro-2,2-dimethoxycyclooctanone oxime as determined by elemental analysis and nuclear magnetic resonance spectroscopy.

Workup

  1. additionafter the addition
  2. additionThe contents were then treated

Sources & evidence

ORD record
ord-425e9f96eb4d4746a0b2b086c9638609
Source dataset
uspto-grants-1979_02
Patent number
US04140717

Reaction notes

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